The MOD is significant when planning dives using gases such as heliox, nitrox and trimix because the proportion of oxygen in the mix determines a maximum depth for breathing that gas at an acceptable risk. There is a risk of acute oxygen toxicity if the MOD is exceeded.[1] The tables below show MODs for a selection of oxygen mixes. Atmospheric air contains approximately 21% oxygen, and has an MOD calculated by the same method.
Safe limit of partial pressure of oxygen
Acute, or central nervous system oxygen toxicity is a time variable response to the partial pressure exposure history of the diver and is both complex and not fully understood.
Central nervous system oxygen toxicity manifests as symptoms such as visual changes (especially tunnel vision), ringing in the ears (tinnitus), nausea, twitching (especially of the face), behavioural changes (irritability, anxiety, confusion), and dizziness. This may be followed by a tonic–clonic seizure consisting of two phases: intense muscle contraction occurs for several seconds (tonic phase); followed by rapid spasms of alternate muscle relaxation and contraction producing convulsive jerking (clonic phase). The seizure ends with a period of unconsciousness (the postictal state).[2][3] The onset of seizure depends upon the partial pressure of oxygen in the breathing gas and exposure duration. However, exposure time before onset is unpredictable, as tests have shown a wide variation, both amongst individuals, and in the same individual from day to day.[2][4][5] In addition, many external factors, such as underwater immersion, exposure to cold, and exercise will decrease the time to onset of central nervous system symptoms.[6] Decrease of tolerance is closely linked to retention of carbon dioxide.[7][8][9] Other factors, such as darkness and caffeine, increase tolerance in test animals, but these effects have not been proven in humans.[10][11]
The maximum single exposure limits recommended in the NOAA Diving Manual are 45 minutes at 1.6 bar, 120 minutes at 1.5 bar, 150 minutes at 1.4 bar, 180 minutes at 1.3 bar and 210 minutes at 1.2 bar.[1]
Formula
The formula simply divides the absolute partial pressure of oxygen which can be tolerated (expressed in atm or bar) by the fraction of oxygen in the breathing gas, to calculate the absolute pressure at which the mix can be breathed. (for example, 50% nitrox can be breathed at twice the pressure of 100% oxygen, so divide by 0.5, etc.). Of this total pressure which can be tolerated by the diver, 1 atmosphere is due to surface pressure of the Earth's air, and the rest is due to the depth in water. So the 1 atmosphere or bar contributed by the air is subtracted to give the pressure due to the depth of water. The pressure produced by depth in water, is converted to pressure in feet sea water (fsw) or metres sea water (msw) by multiplying with the appropriate conversion factor, 33 fsw per atm, or 10 msw per bar.
In feet
In which pO2 is the chosen maximum partial pressure of oxygen in atmospheres absolute and the FO2 is the fraction of oxygen in the mixture. For example, if a gas contains 36% oxygen (FO2 = 0.36) and the limiting maximum pO2 is chosen at 1.4 atmospheres absolute, the MOD in feet of seawater (fsw)[Notes 1] is 33 fsw/atm x [(1.4 ata / 0.36) − 1] = 95.3 fsw.[12]
In metres
In which pO2 is the chosen maximum partial pressure in oxygen in bar and the FO2 is the fraction of oxygen in the mixture. For example, if a gas contains 36% oxygen and the maximum pO2 is 1.4 bar, the MOD (msw) is 10 msw/bar x [(1.4 bar / 0.36) − 1] = 28.9 msw.
Tables
Maximum Operating Depth (MOD) in feet sea water (fsw) for pO2 1.2 to 1.6
MOD (fsw)
% oxygen
4
8
12
16
20
21
24
28
32
36
40
50
60
70
80
90
100
Maximum pO2 (bar)
1.6
1287
627
407
297
231
218
187
156
132
114
99
73
55
42
33
26
20
1.5
1205
586
380
276
215
203
173
144
122
105
91
66
50
38
29
22
17
1.4
1122
545
352
256
198
187
160
132
111
95
83
59
44
33
25
18
13
1.3
1040
503
325
235
182
171
146
120
101
86
74
53
39
28
21
15
10
1.2
957
462
297
215
165
156
132
108
91
77
66
46
33
24
17
11
7
These depths are rounded to the nearest foot.
Maximum Operating Depth (MOD) in metres sea water (msw) for pO2 1.2 to 1.6
MOD (msw)
% oxygen
4
8
12
16
20
21
24
28
32
36
40
50
60
70
80
90
100
Maximum pO2 (bar)
1.6
390
190
123
90
70
66
57
47
40
34
30
22
17
13
10
8
6
1.5
365
178
115
84
65
61
53
44
37
32
28
20
15
11
9
7
5
1.4
340
165
107
78
60
57
48
40
34
29
25
18
13
10
8
6
4
1.3
315
153
98
71
55
52
44
36
31
26
23
16
12
9
6
4
3
1.2
290
140
90
65
50
47
40
33
28
23
20
14
10
7
5
3
2
These depths are rounded to the nearest metre.
See also
Oxygen toxicity – Toxic effects of breathing oxygen at high partial pressures
Minimum operating depth – Depth above which the oxygen concentration is too low to breathe safely
Notes
^Feet sea water (fsw) is a unit of pressure. One fsw is equal to the hydrostatic pressure exerted by a standard sea water column of 1 foot height at normal Earth gravity. 33 fsw is approximately equal to one standard atmosphere (atm). A pressure indicated in fsw is gauge pressure (relative to surface pressure) unless specified.
References
^ abcLang, M.A. (2001). DAN Nitrox Workshop Proceedings. Durham, NC: Divers Alert Network. p. 52. Archived from the original on October 24, 2008. Retrieved 21 November 2012.
^Bitterman, N (2004). "CNS oxygen toxicity". Undersea and Hyperbaric Medicine. 31 (1): 63–72. PMID15233161. Archived from the original on August 20, 2008. Retrieved 29 April 2008.
^Richardson, Drew; Menduno, Michael; Shreeves, Karl, eds. (1996). "Proceedings of rebreather forum 2.0". Diving Science and Technology Workshop: 286. Archived from the original on September 15, 2008. Retrieved 20 September 2008.
Clark, James M; Thom, Stephen R (2003). "Oxygen under pressure". In Brubakk, Alf O; Neuman, Tom S (eds.). Bennett and Elliott's physiology and medicine of diving (5th ed.). United States: Saunders. pp. 358–418. ISBN978-0-7020-2571-6. OCLC51607923.
Lang, Michael A, ed. (2001). DAN nitrox workshop proceedings. Durham, NC: Divers Alert Network, 197 pages. Archived from the original on October 24, 2008. Retrieved 20 September 2008.
U.S. Navy Supervisor of Diving (2011). U.S. Navy Diving Manual(PDF). SS521-AG-PRO-010 0910-LP-106-0957, revision 6 with Change A entered. U.S. Naval Sea Systems Command. Archived from the original(PDF) on 2014-12-10. Retrieved 29 Jan 2015.