苯基甲基二氯硅烷

苯基甲基二氯硅烷
别名 二氯(甲基)苯基硅烷
识别
CAS号 149-74-6  checkY
性质
化学式 C7H8Cl2Si
摩尔质量 191.13 g·mol−1
密度 1.187 g/cm3[1]
熔点 −53 °C[1]
沸点 205~206 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

苯基甲基二氯硅烷是一种有机硅化合物,化学式为C7H8Cl2Si,被美国环境保护局(EPA)列入极度危险物质列表[2]。它可由甲基苯基硅烷維基數據Q63399055三氯异氰尿酸二氯甲烷中反应制得[3]。它和卤代芳烃在氢氧化钾存在下、碳催化下发生偶联反应,可以得到相应的芳基苯[4]

参考文献

  1. ^ 1.0 1.1 1.2 "Metal-Organics Catalog" physical property data were obtained from Gelest, Inc. of Morrisville, Pennsylvania (US). Retrieved from SciFinder. [2024-03-20].
  2. ^ 40 C.F.R.: Appendix A to Part 355—The List of Extremely Hazardous Substances and Their Threshold Planning Quantities (PDF) July 1, 2008, Government Printing Office, [October 29, 2011], (原始内容 (PDF)存档于February 25, 2012) 
  3. ^ Varaprath, Sudarsanan; Stutts, Debra H. Utility of trichloroisocyanuric acid in the efficient chlorination of silicon hydrides. Journal of Organometallic Chemistry. 2007-04, 692 (10): 1892–1897. doi:10.1016/j.jorganchem.2006.12.032. 
  4. ^ Venkatraman, Sripathy; Huang, Taisheng; Li, Chao-Jun. Carbon-Carbon Bond Formation via Palladium-Catalyzed Reductive Coupling of Aryl Halides in Air and Water. Advanced Synthesis & Catalyis. 2002-06, 344 (3-4): 399–405. doi:10.1002/1615-4169(200206)344:3/4<399::AID-ADSC399>3.0.CO;2-X. 
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