1-苯基-1-丙酮肟 1-苯基-1-丙酮肟 识别 CAS号 2157-50-8  Y 23517-42-2（1E）  Y 23517-38-6（1Z）  Y 性质 化学式 C9H11NO 摩尔质量 149.19 g·mol−1 熔点 53 °C（326 K）[1] 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 1-苯基-1-丙酮肟是一种有机化合物，化学式为C9H11NO，是一种肟。 制备及性质 它可由苯丙酮和盐酸羟胺在乙酸钠存在下反应得到。[2]在十二羰基三钌的催化下，它在苯中可以被一氧化碳脱氧，生成α-乙基亚苄亚胺。[3]在乙腈中，氯化铝或氯化汞催化下，它可以重排为N-苯基丙酰胺。[4][5] 它和苯基溴化镁反应，可以得到2-甲基-3,3-二苯基氮丙环：[6] 参考文献 ^ Trofimov, B. A.; Korostova, S. E.; Balabanova, L. N.; Mikhaleva, A. I. Pyrroles from ketoximes and acetylene. VI. Study of conditions for the reaction of aceto- and propiophenone oximes with acetylene. Zhurnal Organicheskoi Khimii, 1978. 14 (8): 1733-1736. ISSN: 0514-7492. ^ Lincong Sun, Bingxian Liu, Yanlian Zhao, Junbiao Chang, Lingheng Kong, Fen Wang, Wei-Qiao Deng, Xingwei Li. Rhodium( iii )-catalyzed asymmetric [4+1] spiroannulations of O -pivaloyl oximes with α-diazo compounds. Chemical Communications. 2021, 57 (67): 8268–8271 [2021-11-08]. ISSN 1359-7345. doi:10.1039/D1CC02888J （英语）.  ^ Motohiro Akazome, Yasushi Tsuji, Yoshihisa Watanabe. Ruthenium Complex Catalyzed Selective Deoxygenation of Ketoximes to Ketimines. Chemistry Letters. 1990-04, 19 (4): 635–638 [2021-11-08]. ISSN 0366-7022. doi:10.1246/cl.1990.635. （原始内容存档于2021-11-09） （英语）.  ^ Li-Feng Liu, Hua Liu, Hong-Jun Pi, Shuo Yang, Min Yao, Wenting Du, Wei-Ping Deng. Facile AlCl 3 -Promoted Catalytic Beckmann Rearrangement of Ketoximes. Synthetic Communications. 2011-01-31, 41 (4): 553–560 [2021-11-08]. ISSN 0039-7911. doi:10.1080/00397911003629416 （英语）.  ^ Chennan Ramalingan, Yong-Tae Park. Mercury-Catalyzed Rearrangement of Ketoximes into Amides and Lactams in Acetonitrile. The Journal of Organic Chemistry. 2007-06-01, 72 (12): 4536–4538 [2021-11-08]. ISSN 0022-3263. doi:10.1021/jo070297k. （原始内容存档于2021-11-09） （英语）.  ^ Kenneth N. Campbell, James F. McKENNA. THE ACTION OF GRIGNARD REAGENTS ON OXIMES. I. THE ACTION OF PHENYLMAGNESIUM BROMIDE ON MIXED KETOXIMES. The Journal of Organic Chemistry. 1939-05, 04 (2): 198–205 [2021-11-08]. ISSN 0022-3263. doi:10.1021/jo01214a012. （原始内容存档于2021-11-08） （英语）.

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